Document Type : Research Paper
Author
University of Salahaddin - Education of Science College
Abstract
The two oxadiazole new ligands of bis oxadiazol derivatives, have been synthesized by the reaction of (L1)and , oxadiazol-2yl] methane (L2.) with adibic acid in presence of ethnolic solution of potassium hydroxide. The mixture was refluxed for eight hours. The ligands were characterized using IR 1H.NMR13C-NMR and mass spectroscopies .The ( L3 ) was used to synthesize complexes with metals Cu( II ) and pd(II ) . The complexes were studied and identified using IR, UV-VIS spectra and molar conductivity, magnetic susceptibility and atomic absorption techniques. The results exhibited that all complexes have an octahedral structure
Keywords
Main Subjects
- E.I Solomon, K.W Penfield and D.E Wilcox, Structure Bonding (Berlin), 53, (1), (1983).
- W.Clegg, J.C. Lockhar and F.H. musa, J. chem. Soc., Dalton trans, (47- 52), (1986).
- N. Dmeirbas , Turk J. chem. , 29, (125-133) (2005)
- F.H. Musa, M.J. Mahmood and I.F. Mustafa, (Under Publishing in J IBN Al-Haitham pure and app.Sci.).
- W. Kemp, ‘Organic Spectroscopy’ Macmillan Education Ltd, 2nd Edition, pp; 44,56,57,222 (1987)
- A.A. Ikizler and U.E.Demirbas, A. Indion J. pharm. Sci, 5,289,(2000)
- A. Demirbas , N-Duman , A.A Ikizler , A.Acta polo Pharm. Drug Res. 53, 117(1996)
- A.A Ikizler, F.Ucar, N.Demirba I.Yasa, A. Demirbas, T.Genzcr, India J. Pharm Sci. 61,27, (1999)
- G.F.XU, B.Ansong, P.s Bhadury, S. Yang, P.Q. Zhang, L.H.Jin W.Xue, D.Y. Hu and P.Lu, Bioorganic + Medical Chemistry 15,(3766-3774) (2007).
- B.Stuart, B.George and P.Melntyre, ‘ Modern infrared Spectros copy ‘ ; John Wiley & sons , P; 111(1998)
- M.El. Khateeb, H.Gorls and W.Wiegand , Inorganica Chemica, Acta., 360,(705-709), (2007)
- M.M Dawood, F.Ikhali and A.M. seyarn. Polyhedron, 8, 2(1989).
- G. Socrates ‘Infrared Characterstic Group Frequcncies; Macmillan Education Ltd, 2nd Edition, pp. (108-117) (1980).
- R.R Kambile, B-s. Sudha and D.G , Bhadregowda, Turk J. Chem. Soc. 73(2) (131-138) (2008)
- N.Demirbas , Turk J.Chem., 29, 125-133 (2005)
- F.H. Musa and I.A.W. Otman , JIBN Al-Haitham Pure and App Sci., 9(1) , 91-99 (1998)
- L.D Field , S.Sternhel , J.R.Kalmam ‘ Organic Structures from spectra ; , 3rd edition , John Wiley and Sons Ltd, 64 (2005) . 17- E.A. ltete, Ph Thesis, college of Education, University of Baghdad Iraq (1999).
- A.S. salameh and H.A. Tayim ; Poly hedron, 1,543 (1982).
- E.A.Hete, ph. Thesis, college of Education, university of Baghdad, Iraq (1999).
- K.H. Al- Obaidi, A.H. Jassim N.Rassout and Z.A Muhi-Eldeey Iraq J.Sci. , 31,132 (1990)
- B- Crociani, T.B. Bosch, R.P. Palo and V. Bellueo; J.Chem. Soc. (A) , 531 (1970)
- A.Gulko. W.F.Rittencr, G.Ron and G. Schemuckr, J. Inorg Nucl. Chem, 33, 761 ( 1971)
- F.H. Musa, H.A.F-Al- Bayti, I.A.W. Otmah, Iraq. Journal Of Chem., 28 (3) (2002)
- O.H Amin , L.J Al-Hayaly , S.A. Al -Jibori and T.A.k. Al-Al- Allaf , Polyhedron , 23,2013- 2020 (2004)
- W.K.Mehdi and F.H Musa, Journal of Al- Nahrain University , 7 (2) 86-95 (2004)
- D.Sutton, ‘Electronic Spectra of Transition Metal Complex ‘Mc Graw Hill-London, p.p (178-180) (1968)
- W.J Geary; coordination Chemistry Reviewsm, Elsevier Publishing company Amsterdam (1970).
- W.K. Mchdi, ph.d thesis , college of Education Ibn Al-Haitham , University of Baghdad (1999).
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