Document Type : Research Paper

Author

College of Science, University of Al-Anbar

10.37652/juaps.2008.15636

Abstract

ABSTRACT: In high dilution method and in ethanol solution has been reacted two moles (o – phenylendiamin ) with tow moles (2,5 – Hexandion) to yield Macrocyelic Ligand type N4 . This Ligand ( L ) has been reacted with some metal ion to product metal complexes (M L ) where M = Cr+3, Cu+2and Cd+2. The metal complexes were characterized by elemental analysis, (C.H.N), molar conductivities, I.R spectra, UV-Vis., HPLC, and atomic absorption. From the above data the proposed molecular structure for (ML) is octahedral, and Trigonal bipyrimed

Keywords

1. Marcus, Y.; Kertes, S. Exchange and Solvent Extraction of Metal Chelates. Wiley-Interscience; London, 1969.
2. Lauffer, R. B. Chem. Rev., 87, 901, 1987.
3. Parker, K.; Chang, C. A.; Tweedle, M. F. Inorg. Chem, 32, 587, 1993.
4. Kumar, K.; Tweedle, M. F. Pure Appl. Chem, 65, 515, 1992.
5. parker, D. Chem. Soc. Rev, 19, 271, 1990.
6. Lakshmi, B.; Prabhavathi, A.; Devi, M.; Nagarajan, S. J. Chem. Soc. Perkin Trans (1997), 1495 and Refs. Cited Therein.
7. Blight, S. W. A.; Choi, N.; Cummins, W. S.; Evagorou, E. G.; Kelly, J. D.; McPartin, M. J. Chem. Soc. Dalton Trans (1993) 3829 and Refs Cited Therein.
8. Hadzi, D. J. Chem. Soc.  2725,1956.
9. Margerum, J. D. and Sousa, J. A. App. Spectrosc.; 19, 91,1965.
10. Jakels, S. C.; Clavola, J.; Carter, R. C.; Cheek, P. L. and Pascarelli, T. D. Inorg. Chem. 22, 3956, 1983.
11. Shakir, M.; Mohamed, A. K.; Varky, S. P. and Nasman, O. S. M. Indian J. Chem., 35,935, 1996.
12. Prebnadaran, G. P. and Pateic, C. J.; J. Inorg. Nucl. Chem. 13,3316, 1969.
13. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, Inc.; New York (1997).
14. El-Tabl, A. S. and Kasher, T. L. Polish J. Chem. 72,519, 1998.
15. Green Wood, N. N. and Earnshow, A.; Chemistry of the elements, J. Wiley and Sons Inc. New York (1998).
16. Abdul-Rahman, A. A. Ph.D. Thesis, University of Baghdad (2002).
17. Jeboori, M. S. and Abdul-Kareem. Unpublished results.
18. Ramesh, V.; Umasundari, P. and Kalyank Das. Spectrochim. Acta; Part A; 54, 285, 1998.
19. Geary, W. J. Coord. Rev.;, 7 81, 1971.