Document Type : Research Paper

Authors

1 University of Anbar - College of Science - Department of Chemistry

2 Basra University - College of Education for Pure Sciences - Department of Chemistry

Abstract

In this study, a new dimers containing a five-member ring heterocyclic were prepared. Three dimers were prepared from terminal acetelynic compounds by the oxidative coupling reaction . All compounds identification by Measured their melting point and by an infrared spectrometer FT-IR. Dimers were also identified by infrared and 1H-NMR spectra. The liquid crystalline properties of the dimers prepared were studied by an optical polarized microscope(OPM) with a Hot Stage and by (DSC). The dimers D1,D2 showed liquid crystalline properties nematic while the daimer D3 did not appears any liquid crystalline phase.
 

 

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  1. Morrison, R. T., and R. N. Boyd. "Organic Chemistry", 6th ed. New Delhi ; p. 1002 (2002).
  2. Acheson, R.M. "Introduction to the chemistry of heterocyclic compound".3ed ed. (1976).
  3. Jack ,L., J.,  "Heterocyclic chemistry in drug discovery". John Wiley & Sons,USA ,p.5( 2013).
  4. Gheneim, Rana, Catalina Perez-Berumen , Alessandro Gandini. "Diels− Alder reactions with novel polymeric dienes and dienophiles synthesis of reversibly cross-linked elastomers", Macromolecules ,vol. 35(19) ; pp. 7246-7253 (2002).
  5. Su, Deyuan, et al. "Thiazolidine reacts with thioreactive biomolecules." Free Radical Biology and Medicine vol. 104 ; pp. 272-279‏ (2017).
  6. Smith, Janice G.in the" Organic Chemstry"-1 st ed, ISBN 0-07h-39746-2 547-dc22  , (2006).
  7. Francis A.Carey "Organic Chemistry" 4ed,university of irginia (2000).
  8. .Sagadevan, Arunachalam, et al. "Visible Light Copper Photoredox-Catalyzed Aerobic Oxidative Coupling of Phenols and Terminal Alkynes: Regioselective Synthesis of Functionalized Ketones via Triple Bond Cleavage." Journal of the American Chemical Society vol.139(8) ; pp. 2896-2899‏ (2017).
  9. Han, Mengna, et al. "Synthesis, characterization, and properties of thermosets based on the cocuring of an acetylene‐terminated liquid‐crystal and silicon‐containing arylacetylene oligomer." Journal of Applied Polymer Science vo.l 134(33) ; (2017).‏
  10. Se, Kazunori, Hiroshi Ohnuma, and Tadao Kotaka. "Electrical conductivity of urethane-substituted poly (diacetylenes): effect of substituent side groups and molecular weights." Macromolecules vol. 17(10) ; pp. 2126-2131‏ (1984).
  11. Ito, Takeo, Hideki Shirakawa, , Sakuji Ikeda. "Simultaneous polymerization and formation of polyacetylene film on the surface of concentrated soluble Ziegler‐type catalyst solution" , Journal of polymer science: polymer chemistry edition,vol. 12(1) ;pp. 11-20(1974).‏
  12. Chauser, Mikhail Grigor'evich,. "Polymerisation of acetylenes. The structure and electrophysical properties of polyvinylenes" Russian Chemical Reviews , vol. 45(4) ; pp. 348-374(1976).‏
  13. Koz, Banu, Baris Kiskan, and Yusuf Yagci. "Synthesis and characterization of polyacetylene with side-chain thiophene functionality." International journal of molecular sciences vol.9(3) ; pp. 383-393 (2008).
  14. Koz, Banu, Baris Kiskan, and Yusuf Yagci. "Synthesis and characterization of polyacetylene with side-chain thiophene functionality." International journal of molecular sciences ,vol.9(3) ;pp. 383-393 (2008).
  15. مالکوم.ب.ستیفن "کیمیاء البلمرة" ,ترجمة :د.قیس عبد الکریم ابراهیم ,د.کاظم غیاض اللامی ,جامعة البصرة ,قسم الکیمیاء ,ص33 ,(1984).
    1. Lai, Chunqiu, and John A. Soderquist. "Nonracemic homopropargylic alcohols via asymmetric allenylboration with the robust and versatile 10-TMS-9-borabicyclo [3.3. 2] decanes." Organic letters vol.7(5) ; pp. 799-802 (2005).
    2. Son, Ho-Jin, et al. "End-capped silole dendrimers on a carbosilane periphery: potential electroluminescent materials." Organometallics  vol.25(3) ; pp. 766-774 (2006).‏