Document Type : Research Paper

Authors

1 Department of Chemistry, College of Science, University of Baghdad

2 Central Labaratory, Ministry of Health, Baghdad, Iraq

Abstract

The concentrations of Pb2+ and Cd2+ in the blood of 30 persons working in the Liquid Battery Factory in Baghdad were measured applying the Differential Pulse Polarography (DPP) method. It was found that for the majority of the blood samples, the Pb2+ concentration valueswere acceptable and within the acceptable natural limits(10-20µg/100ml).Exceptionsare 4 samples which showed higher lead ion concentrations. The infected persons worked at a location with high lead presence in the factory. As for the measured Cd2+ concentrations, the results for all the blood samples showed normal values, within the defined acceptable concentration (5.4µg/100ml). However, onconsidering the other defined acceptableconcentration, as reported in the literature, (3µg/100ml), three workmen were found, to have higher Cadmium ion concentration in their blood. It was also found that, compared with the calibrated DPP results, themeasured Atomic Absorption Spectroscopic (AAS) results showed much higher concentration values and should therefore be not acceptable. The measured concentrationsofboth ionswere independent from the age of the workers. Inspections for the presence of Cu2+ ions in the blood samples failed in detecting any traces of it.
 

 

Keywords

Main Subjects

  1. a- Jaishanker M., Tseten T., Anbalagan N., Mathew B.B. and Beere K.N.Toxicity, mechanism and health effects of some heavy metals., 2014, 7(2), pp: 60-72. b- Rahman A. Bioremediation of Toxic Metals for Protecting Human Health and the Ecosystem,ÖrebroUniversit., 2016.
  2. Brochin R., Leone S., Phillips D., Shepard N., Zisa D. and Angerio A. The cellular effect of Lead poisoning and its clinical picture. The Georgetown Undergraduate Journal of Health Science (GUJHS), 2008, 5(2), pp: 1-8.
  3. Madgal V.,Madaan N., Mudgal A., Sinhg R.B., and Mishra S. Effect of toxic metals on human health. The Open Nutracunticals J.,2010, 3, pp: 94-99.
  4. Bernard A. Cadmium and its adverse effects on human health. Indian J. Med. Res.2008,128(4), pp: 557-564.
  5. Jakubowski M.Exposure to chemical factores in the environment. In: Biological Monitoring . Lodz, Nofer Institute of Occupational Medicine; 1997.
  6. Wasowicz W., Gromadzinska J. and Rydzynski K., Blood concentration of essential trace elements and heavy metals in workers exposed to Lead and Cadmium; International Journal of Occupational Medicine and Environmental Health, (IJOMEH),2001, 14(3), pp: 223-229
  7. Thomas J.A., Brogan W.C., 3rd, 1983, Some actions of lead on the sperm and on the male reproductive system,Am. J. Ind. Med.,4(1-2), pp:127–134.
  8. Nordberg G.F., Fowler B.A., Nordberg M. and Friberg L.T., Handbook of the Toxicology of Metals, 2ndedn., (1986), Vol. I, Elsevier, Amsterdam, New York, Oxford.
  9. Lindh U., Brune D., Nordberg G., Wester P.O. 1980, Levels of antimony, arsenic, cadmium, copper, lead, mercury, selenium, silver, tin and zinc in bone tissue of industrially exposed workers.Sci. Total Environ.16(2), pp: 109-116.

10. Clayton, George D., Clayton and Florence, E. Clayton, Patty's Industrial Hygiene and Toxicology. Toxicology,(1995), 4rdEdn., Vol. 2E, John Wiley and Sons, New York.

11. Hartwig A.Role of DNA repair inhibition in lead- and cadmium-induced genotoxicity: a review,Journal of Environ Health Perspect.1994, 102(3), pp: 45–50.

12. Cooper,W.C. Ann. Ny. Acad. Sci.,1976. 271, pp: 250–259.

13. Heyrovsky, J. and Zuman, P. Practical Polarography, Academic Press, New York and London (1968).

14. De Levie, R., Principles of Quantitative Chemical Analysis, The McGraw–Hill Companies, Inc., London (1997).

15. Laborda, Eduardo; Gonzalezm Joaquin; Molina, Angela (2014); Recent Advances on the theory of Pulse Techniques; a mini Review, Electrochemistry Communications, 43, pp: 25-30.

16. Bard A.J. and Faulkner L. R., Electrochemical Methods: Fundamental and Applications, 2nd ed. John Wiley and Sons, New York, NY, USA, 2001.

17. Shirley, Benar and Miller,1949, J. Anal. Chem. 21(9), pp: 1123–1125.

18. Valenta, P. Nurnberg, H. W. Stoeppler, 1979, Z. Anal. Chem. 285, pp: 25-34.