Document Type : Research Paper

Authors

Department of Chemistry ,College of Science, University of Anbar,Anbar.Iraq.

10.37652/juaps.2017.175963

Abstract

In this work, the used three main polymers in industry, they are (Poly styrene, Poly vinyl chloride, and Poly methyl metha acrylate) studied under the microwave radiation. The Homo Polymers and Co-Polymers and Blended Polymers using a hand molding casting. Degradation studies were carried out using commercial microwave oven at Different Microwaves power of (120,180,220,280,320W) At a fixed time (5 sec) for all experimental. The specimens were exposed to microwave radiation with multiple time (0.0, 5, 10, 15, 20) second, A degradation were followed via the decreases in average of molecular weights (Mw', Mn) and Increase and decrease of the measurements of the mechanical properties of which have been tested.

Main Subjects

[1] REFER1. Zhu HM, Jiang XG, Yan JH, Chi Y, Cen KF, Appl Pyrolysis, 82, 1-9, (2008 (.
[2] Savrik SA, Erdogan BC, Balkose D, Ulku . J .Appl. Polym Sci, 116, 1811-1822, (2010).
[3]  Prachaya warakorn J, Khamsri J, Chaochan chaikul K, Sombat sompop N, J Appl.Polym Sci, 102, 598-606, (2006).
[4]Mojtaba  Saeedi ،  Ismaeil  Ghasemi ،and  Mohammad  Karrabi ،Iranian  Polymer Journal،20 (5),، 423-432, (2011)[5 ] Saburo Moriwaki،Motoi Machida،Hideki Tatsumoto، Yasufumi   Otsubo, Applied Thermal Engineering 26،745 – 750 Elsevier Ltd. (2006)
[6] Makiko Doi،Kazuhiko Fukatsu، Ryota Shinohara،Masataka Hai kibutu gakkaisi,15، 294 - 301. (2004)
[7]  Seung  Hwan  Lee,  Won  Gu  Lee,  Bong  Geun  Chung ،Ali  Khadem  hosseiniMacromol .Rapid Commun، 30,1382–1386، (2009)
[ 8]Z. Zhao, Z. Li،Q .Xia،H. Xi،Y .Lin،  Eur .Poly. J . 44، 1217.  (2008) .
[9] C. A . Puger، R .L . Carrier, B. Sun, K. S. Ziemer, D. D. Burkey,  Macromol. Rapid Commun, 30, 126. (2009).
[10] C. Oliver Kappe · Doris Dallinger،Mol Divers 13:71–193،(2009)
[11]36.    Ondruschka    B,    Bonrath    W    Microwave-assisted    chemistry    astock taking.Chimia 60:326–329, (2006).
[12]  Polshettiwar  V,   Varma  RS  Aqueous   microwave   chemistry ،Chem  .SocRev37:1546–1557 (2008)
[13] Coquerel Y, Rodriguez J، Microwave-assisted olefin Metathesis .Eur. J. Org. Chem 1125–1132 (2008) .