Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives

Hamd Shehab, Omar

doi:10.37652/juaps.2010.43921

Document Type : Research Paper

Author

Omar Hamd Shehab

AL-Anbar University- College of Education for women

10.37652/juaps.2010.43921

Abstract

Acetylenic amine derived from secondary amines such as piperidine , pyrolidine and
diethyl amine were synthesized as charge transfer donor have been treated with receptor I2,Br2 and
DDQ (DDQ = 2,3-Dichloro-5,6-Dicyano-p-Benzoquinone) to prepare transitional charge complexes .
Benesi-Heldbrand equation have been used at (λmax)for formation complexes to calculate potential
ionize. Calculation for acetylenic amines derivatives at the first time from transitional energy with
studied receptor and calculated equilibrium constant

Keywords

Main Subjects

Chemistry

References

1- T.F.Rufledge, "Acetylenic compounds", Academic press, London and New York (1969).

2- R.E. Mecmahone, J.Pharma.Sci., 55,457,(1966).

3- N.R.Eston, J.Mol.Chem., 9,456, (1966).

4- M.A.Schwartz, P.Brown and F.M Vane, Arch. Biochem., 121,pp509-516,(1967).

5- W.Wernick and R. Wolffenstein, Chem. Ber., 31,1553(1889).

6- V.B.Mochalin and T.S. Minervina, Zr. Org. Khim.,1(10),1726 (1965).

7- H.A.Benesi and J.H.Heldbrand, J.Am.Chem.Soc., 71,2703 (1949).

8- R.Foster,"Charge-Transfer Complexes ", Academic Press, London and New York (1969).

Journal of University of Anbar for Pure Science

Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives

References

References

Volume 4, Issue 2
August 2010
Page 24-26

Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives

References

References

Volume 4, Issue 2August 2010Page 24-26

Volume 4, Issue 2
August 2010
Page 24-26