Document Type : Research Paper
Authors
1 University Of Anbar - College of Science
2 University of Anbar - College of Science
Abstract
A new potentiometric method was adopted for the determination of ascorbic acid , malonic acid and resorcinol using iodine (dissolved in glacial acetic acid) as oxidant . The liberated iodide was monitored using sulphide and cyanide ion-selective electrodes compared with platinum electrode . The potential changes were sufficiently sharp (in the range of 280-300mV/0.1ml) for establishing the end points over a range of 0.001-0.100M of these reductants . The method was found accurate for determination of these reductants individually and in their mixtures .
Keywords
- Ion
- Selective Electrodes
- Ascorbic acid
- oxidation
- reduction potential
- Iodimetric technique
- Resorcinol
- Malonic acid
Main Subjects
- Khlifa,H., Abedl-Ghani,H.T., and Rizk, M.S. Microchem.J.,29,(1984)195.
- Rizk, M.S., Issa, Y.M., Kalifa, H. and Ali, A.A.,Egypt J. chem., 28 (1985) 99.
- Issa, Y.M, Rizk, M.S, Kalifa, H., and Ali, A.A.,Egypt J. Chem., 27, (1984)593 .
- Comstock, M.J, "Ascorbic Acid Chemistry" Paul, A., Seibe, T. and Bert, M. (1982).
- Kumar, K.G. and Indrasenan , P., Talanta, 37, (1990) 269.
- Gowda, H.S and Ahmed, S.A., Anal. Chim. Acta, 99, (1978), 343.
- Szekeres, L. and Kallner, A., Chemist Analyst, 55, (1966) 77.
- Nasser, T.A.K., Al-Rikabi, A.M and Mansoor, Th.A., Anal. Letter, 20, (1987) 627.
- Janghel, E.K, Gupta, M.K. and Rai, J.K., Talanta, 72 (2007) 1013.
- Salkic, M. and Kubicek, R,European., J. of Scientific Research, 123(3) (2008),35,.
- Wu, X.Y., Diao, C., Sua, J., Yang, Y. and Wang, S., Talanta, 59 (2003) 95.
- Raoof, J.B., Ojani, R., Hosseinzadeh, R. and Ghasemi, V., Analytical Sciences, 19 (2003)1251.
- Eckschlager, K., Horsak, I. and Siska, J.V., Chem. Commun. 35 (1979) 2353.
- Sulaiman, S.T., Analyst 109(1984) 739.
- Foka, I.P., Faimatsiya, 33,(1984) 64.
- Yang, Z., and Jin, J., Fenxi Huaxue, 12 (1984), 565.